Recent Advances in Electroorganic Synthesis

内容紹介

目次

1. Electrooxidation

・ Some Recent Applications of the Kolbe-Electrolysis in Organic synthesis
・ Electrochemical Formation of Chemical Bonds. Coupling Reactions and Mixed Electrolysis
・ Cyclization, alpha-Cleavage and Substitution Processes in the Anodic Oxidation of Alkyl Isothiocyanates
・ Anodic Oxidation of 1,2,3,4-Tetrahydrocarbazole in the Presence of TEMPO (2,2,6,6-Tetramethylpiperidyl-1-oxy)
・ Reactions of Electrochemically Generated Triphenylphosphine Radical Cation with 1,3-Dicarbonyl Compounds and with Olefins
・ Electrophilic Additions to Alkenes and Dienes
・ Electrochemical Thiocyanation of Indoles
・ Some Synthetic Reactions of the Electrogenerated Radical Species
・ Electrochemical Generation of Reactive Nitrogen Species and their Reactions
・ Formation of Heterocyclic Derivatives by Anodic Oxidation of Allenes and Hetero-allenes
・ Cross-coupling of Anodically Generated Phenoxy Radicals
・ Oxygen Heterocycles by Anodic Oxidation of Phenols and Biphenylols
・ The Chlorination of Aromatic Compounds by Two-phase Electrolysis
・ Mechanism of Anodic Fluorination
・ Halogenation of Poly(vinyltoluene) by Electrolysis in Organic/Water Suspension System
・ Reactions of Electrochemically Generated Olefin Radical Cations with Molecular Oxygen
・ Electrochemically Induced [4+2]-Cycloadditions
・ Oxidative Cycloaddition of 1,3-Diketone and Olefin Using Electroorganic Chemistry
・ Anodic Oxidation of beta-Lactams
・ Chemical Modification of Oleanene Oligoglycosides by Means of Anodic Oxidation
・ Quinolide Protective Groups/Electrochemical Techniques
・ Remote Acetamidation of Steroids by Anodic Oxidation
・ Electroorganic Synthesis of Some Bioactive Substances
・ CH-Functionalization of Fatty Acids and Steroids

2. Indirect Electrooxidation

・ Some New Developments in the Electrochemistry of Organo-Sulfur Compounds
・ N-Hydroxyphthalimide as a Mediator in the Anodic Oxidation of Organic Compounds
・ Anodic Oxidation of 2-Methylnaphthalene by Use of Metal Oxide Modified Graphite Electrode
・ Electro-paired Oxidation of Hydrocarbons
・ Electrocatalytic Oxidation of Methanol on Modified Electrodes
・ Indirect Oxidation of Halogenated Alcohols with RuO₄
・ Functionalization of Organic compounds at the Nickel Hydroxide Electrode
・ Electrochemical Production of Alkylation Catalysts

3. Electroreduction

・ Intramolecular Reductive Coupling as a Step in the Synthesis of Certain Natural Products
・ Synthetic Applications of Electron-transfer Reactions
・ Enhanced Organic Electrochemistry in Cyclodextrin System
・ Contributions to the Cathodic Electroorganic Synthesis
・ Electroreduction of 6H-1,3-Thiazines and Related Compounds
・ Electrochemical Reduction of 2-Benzylidene-2H-3-benzofuranone Derivatives
・ Electroorganic Synthesis of m-Hydroxybenzyl Alcohol. Preparation of m-Phenoxybenzyl Alcohol for the New Insecticide Ethofenprox
・ Electrochemistry of Organic Acceptor Compounds : Aromatic Anhydrides
・ A Novel Electrochemical Isomerization of cis-Cinnamyl Alcohols to trans-Cinnamyl Alcohols
・ 3,3-Dichlorotetrahydrofurans by Reductive Addition of 3-Bromo-1,1,1-trichloroalkynes to Carbonyl Compounds
・ Proton Transfers in the Electrochemical Reduction of 2-Bromoisobutyramides
・ Cathodic Synthesis of Diphenylmethane at Different Metal Electrodes
・ A New Electroreductive Crossed Coupling Reaction of alpha-Hydroxycarbamates with Activated Olefins in the Presence of Trimethylsilyl Chloride
・ Cathodic Reduction of 2- and 4-Cyanopyridine at High Surface Area Electrodes
・ Stereochemistry of the Electrochemical Reduction of beta-Aminoketones
・ Cathodic Desulfinylation of Some Organosulfur Compounds Prepared from FAMSO
・ The Conductive Sulfur/Carbon Cathode Used as an Efficient Tool for Introducing Sulfur Atom(s) in Electroactive Systems
・ Syntheses Involving the Electrolysis of Tetraphenylbutatriene and Its Reduction Products
・ Electrochemical Transesterification and Amidation
・ A New Electrogenerated Base of Phenazine and Its Synthetic Applications

4. Metal-Mediated Electroreduction

・ Electroorganic Synthesis of Natural Products Mediated by Vitamin B₁₂
・ Electrosynthesis beyond the Conventional Cathodic Potential Window
・ Sacrificial Anodes in Electroorganic Synthesis
・ Mechanism of the Electroreduction of Benzene Rings on Mercury Cathode
・ Metal Powders as Intermediates in Electrosynthesis
・ Electroreductive and Zn-Promoted Reductive Cyclization of 2-Substituted Nitrobenzenes
・ Electro-Allylation of Carbonyl Compounds with a Pb(0)/Pb(II) and Br^-/Br⁺ Redox System
・ Lanthanide-mediated Electrochemically-initiated Aldol Condensation
・ Organic Reactions Catalyzed by Electrogenerated Organometallic Species. Activation of Hydrocarbons and Carbon Monoxide and Related Reactions
・ Carbon Dioxide Activation through the Co(II)-Salophen Complex
・ Synthesis and Properties of Vitamin B₁₂-Modified Electrodes
・ Synthesis of Oxygen Heterocycles by Ring-closure of Ketones
・ Oxidation of Benzene to Phenols with Molecular Oxygen Using Cu(I)/Cu(II) Couple as a Mediator
・ Direct Phenol Synthesis from Benzene by Means of Electro-reduction of Oxygen in Trifluoromethanesulfonic Acid

5. Conductive Polymer, Electropolymerization, Electrode Surface

・ Electrosynthesis of Electroactive Polymer Films
・ Electrochemical Preparation of Conductive Enzyme Membrane
・ Conducting Polymers Which Bind and Release Organic Ions in Response to an Electrical Signal
・ Preparation of Semiconductive Polymers by the Electrolytic Polymerization of Vinyl Monomers
・ Functionalyzed Conducting Polymer Membranes Prepared by Electrochemical Method and their Functions
・ The Formation by Anodic Means of New Versatile Conducting Polymers for the Building of Modified Electrodes
・ Electrosynthesis of Polyaniline and Its Properties
・ Isotopic Effect in Electropolymerization of Thiophene and Determination of Mean Conjugated Chain Length
・ Design of Asymmetric Polythiophene Electrodes
・ Photoelectrochemical Synthesis of Phenol on Photoexcited Semiconductor Surface
・ In-Situ Observation of Organic Compounds at the Electrode Surface Using Spectroscopies
・ Selective Electrolysis on poly (perfluoro sulfonic acid)-Coated Electrode
・ Initial Stage of Electroorganic Reactions at Photoexcited Semiconductor Surface
・ Close Look at Electrode Surface by Surface Enhanced Raman Scattering during Reduction of Nitrobenzene
・ Reaction Selectivity in SPE Electroorganic Syntheses--Effects of Nafion on Reduction of Aromatic Nitro Compounds--

6. Industrial Application & Cell Design

・ The Recent Status of “The Manufacturing Process of Adiponitrile”
・ Investigations Relating to Advances in Electro-Organic Technology
・ A Few Industrial Applications of Electro-Organic Chemistry
・ Electrochemical Hydrodimerization of Formaldehyde to Ethylene Glycol
・ The ICI (Mond) FM21 Cell as a Multi-Purpose Electrolyser
・ Electrochemical Process Design and Scale-Up in Fine Chemical Application
・ Reaction Techniques for the Anodic Preparation of Benzaldehydes
・ Some Electro-Organic Technologies Implemented in India
・ The Indirect Electrolytic Oxidation of Aromatic Derivatives
・ The Preparation of Tetramethylammonium Hydroxide (TMAH) by Electrolyzing Tetramethylammonium Chloride (TMAC)